By Myriam Illemassène, Jane Perrone, OECD, Federico J. Mompean

ISBN-10: 0080457525

ISBN-13: 9780080457529

ISBN-10: 0444514023

ISBN-13: 9780444514028

This quantity is a part of the sequence on "Chemical Thermodynamics", released below the aegis of the OECD Nuclear strength organization. It encompasses a severe overview of the literature on thermodynamic info for compounds of complexes of oxalate, citrate, EDTA and iso-saccharinate with uranium, neptunium, plutonium, americium, technetium, selenium, nickel and zirconium. A assessment crew, composed of 5 across the world famous specialists, has seriously reviewed all of the clinical literature containing chemical thermodynamic info for the above pointed out platforms. the result of this serious assessment conducted following the tips of the OECD NEA Thermochemical Database undertaking were documented within the current quantity, which includes tables of chosen values for formation and response thermodynamical houses and an in depth bibliography. Contributed by means of: Wolfgang Hummel (Chairman), Paul Scherrer Institute, Switzerland, Giorgio Anderegg, Swiss Federal Institute of know-how (ETH), Switzerland, Linfeng Rao, Lawrence Berkeley nationwide Laboratory, usa, Ignasi Puigdom?nech, Swedish Nuclear gas and Waste administration Co. (SKB), Sweden, and Osamu Tochiyama, Tohoku college, Japan. * serious overview of all literature on chemical thermodynamics for compounds and complexes of oxalate, citrate, EDTA and iso-saccharinate with U, Np, Pu, Am, Tc and Se, Ni and Zr.* Tables of steered chosen Values for thermochemical homes* Documented overview method* Exhaustive bibliography* meant to fulfill specifications of radioactive waste administration group* priceless reference resource for the actual, analytical and environmental chemist.

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Extra resources for Chemical Thermodynamics of Compounds and Complexes of U, Np, Pu, Am, Tc, Se, Ni and Zr With Selected Organic Ligands, Volume 9 (Chemical Thermodynamics)

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The designator (sin) is used for substances in solution without specifying the actual equilibrium composition of the substance in the solution. 3). 3) involves an HC1 solution, in which the thermodynamic properties of H2O(sln) may not be the same as those of the pure liquid H2O(1). In dilute solutions, however, this difference in the thermodynamic properties of H2O can be neglected, and H2O(sln) may be regarded as pure H2O(1). Example: UO2Cl2(cr) + 2HBr(sln) ^ UO2C12 • 3H2O(cr) ^ UO3(y) + 2HCl(sln) ^ UOBr2(cr) + 2HCl(sln) UO2C12 • H2O(cr) + 2 H2O(1) UO2Cl2(cr) + H2O(sln) (II.

The situation is more complicated for Na and K interactions. ". As discussed in Chapters V, VI, VII and VIII the answer is different for different ligands. In the case of oxalate, Na and K interactions are treated solely as specific ion interactions. In the case of edta, Na and K complexation constants had to be included in the speciation models. Na and K interactions with citrate are in between these two extremes. In the course of the review process both variants have been evaluated and compared, and finally the review team decided to treat the effects of Na and K on citrate solely as rather strong specific ion interactions.

8 with water. 5 capacity of Processes Chemical processes are denoted by the operator A, written before the symbol for a property, as recommended by IUPAC [82LAF]. An exception to this rule is the equilibrium constant, cf Section II. 6. , the Gibbs energy of formation, AfGm, the enthalpy of sublimation, A sub // m , etc. The abbreviations of chemical processes are summarised in Table II-3. Table II-3: Abbreviations used as subscripts of A to denote the type of chemical process. Subscript of A Chemical process at separation of a substance into its constituent gaseous atoms (atomisation) dehyd elimination of water of hydration (dehydration) dil dilution of a solution f formation of a compound from its constituent elements fus melting (fusion) of a solid hyd addition of water of hydration to an unhydrated compound mix mixing of fluids r chemical reaction (general) sol process of dissolution sub sublimation (evaporation) of a solid tr transfer from one solution or liquid phase to another trs transition of one solid phase to another vap vaporisation (evaporation) of a liquid The most frequently used symbols for processes are AfG and AfH, the Gibbs energy and the enthalpy of formation of a compound or complex from the elements in their reference states (cf.

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Chemical Thermodynamics of Compounds and Complexes of U, Np, Pu, Am, Tc, Se, Ni and Zr With Selected Organic Ligands, Volume 9 (Chemical Thermodynamics) by Myriam Illemassène, Jane Perrone, OECD, Federico J. Mompean


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